Blar i forfatter "Ganguly, Sumit"
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Ligand Noninnocence In Manganese, Iron, and Cobalt Corroles
Ganguly, Sumit (Doctoral thesis; Doktorgradsavhandling, 2017-11-30)In recent years, first-row metallocorroles have provided some of the most instructive examples of noninnocent ligands. This thesis presents a study of some 50 iron, manganese, and cobalt corrole complexes with different axial ligands (including approximately 30 new compounds and 6 new X-ray structures) with emphasis on their noninnocent/innocent character. UV-vis spectroscopy has for some time ...